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F. Matthias Bickelhaupt

Chemiker

Name	F. Matthias Bickelhaupt
Zeit	1990- (Wirkungsdaten)
Ort	Niederlande
Geschlecht	männlich
Akademischer Grad bzw. Titel	Prof. Dr.
Beruf	Chemiker (charakteristischer Beruf)
Variante	Friedrich Matthias Bickelhaupt Friedrich Bickelhaupt Matthias Bickelhaupt
Beziehung	Vrije Universiteit Amsterdam Radboud Universiteit Nijmegen Theoretische Chemie (Thema)
Quelle	Homepage: http://www.few.vu.nl/~bickel/ (Stand: 19.02.2021)
Datensatztyp	Person
GND-Nummer	1227745869
Datensatz-ID	1227745869
Beteiligt an alle anzeigen Cobalt‐Catalyzed Enantio‐ and Regioselective C (sp 3)−H Alkenylation of Thioamides Cobalt‐Catalyzed Enantio‐ and Regioselective C (sp 3)−H Alkenylation of Thioamides More Electropositive is More Electronegative: Atom Size Determines C=X Group Electronegativity Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion Front Cover: Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion (ChemPhysChem 1/2024) Stabilization of Diborynes versus Destabilization of Diborenes by Coordination of Lewis Bases: Unravelling the Dichotomy Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion Origin of the Bürgi‐Dunitz Angle S N 2 versus E2 Competition of Cyclic Ethers Origin of the Bürgi‐Dunitz Angle Probing Polar‐π Interactions Between Tetrazoles and Aromatic Rings ** Intermolecular Covalent Interactions: Nature and Directionality The Search for Enhanced σ‐Donor Ligands to Stabilize Boron‐Boron Multiple Bonds Palladium-catalyzed activation of H n A–AH n bonds (AH n = CH 3, NH 2, OH, F) Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn =N, P, As) Insertion of CO2 and CS2 into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer How Bases Catalyze Diels‐Alder Reactions The abnormally long and weak methylidyne C–H bond Methyl Substitution Destabilizes Alkyl Radicals Methyl Substitution Destabilizes Alkyl Radicals How Ionization Catalyzes Diels–Alder Reactions How Ionization Catalyzes Diels–Alder Reactions C−X Bond Activation by Palladium: Steric Shielding versus Steric Attraction How Ionization Catalyzes Diels‐Alder Reactions Corrigendum: Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions C (sp n)−X (n=1–3) Bond Activation by Palladium B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order Probing the Lewis Acidity of Boronic Acids through Interactions with Arene Substituents C (sp n)−X (n=1–3) Bond Activation by Iron Palladium‐Catalyzed Activation of Carbon–Halogen Bonds: Electrostatics‐Controlled Reactivity B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order Front Cover: B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order (ChemistryOpen 2/2022) The Chemical Bond: When Atom Size instead of Electronegativity Difference Determines Trend in Bond Strength The Chemical Bond: When Atom Size Instead of Electronegativity Difference Determines Trend in Bond Strength Radical Scavenging Potential of the Phenothiazine Scaffold: A Computational Analysis Origin of the α‐Effect in S N 2 Reactions Origin of the α‐Effect in S N 2 Reactions Origin of the α‐Effect in S N 2 Reactions Origin of the α‐Effect in S N 2 Reactions Lewis Acid‐Catalyzed Diels‐Alder Reactions: Reactivity Trends across the Periodic Table How Lewis Acids Catalyze Ene Reactions On the Origin of Regioselectivity in Palladium‐Catalyzed Oxidation of Glucosides Proton Transfer and S N 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx Proton Transfer and S N 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx The Gauche Effect in XCH 2 CH 2 X Revisited A Quantitative Molecular Orbital Perspective of the Chalcogen Bond Switch From Pauli‐Lowering to LUMO‐Lowering Catalysis in Brønsted Acid‐Catalyzed Aza‐Diels‐Alder Reactions A Quantitative Molecular Orbital Perspective of the Chalcogen Bond Front Cover: A Quantitative Molecular Orbital Perspective of the Chalcogen Bond (4/2021) Nature of Alkali‐ and Coinage‐Metal Bonds versus Hydrogen Bonds Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement Do Sulfonamides Interact with Aromatic Rings? How Oriented External Electric Fields Modulate Reactivity How Oriented External Electric Fields Modulate Reactivity Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length Bismutamide als einfache Vermittler hochselektiver Pn−Pn‐Radikal‐Kupplungsreaktionen (Pn=N, P, As) Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As) Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As)

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Katalog der Deutschen Nationalbibliothek

F. Matthias Bickelhaupt

Cobalt‐Catalyzed Enantio‐ and Regioselective C (sp 3)−H Alkenylation of Thioamides

Cobalt‐Catalyzed Enantio‐ and Regioselective C (sp 3)−H Alkenylation of Thioamides

More Electropositive is More Electronegative: Atom Size Determines C=X Group Electronegativity

Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion

Front Cover: Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion (ChemPhysChem 1/2024)

Stabilization of Diborynes versus Destabilization of Diborenes by Coordination of Lewis Bases: Unravelling the Dichotomy

Blueshift in Trifurcated Hydrogen Bonds: A Tradeoff between Tetrel Bonding and Steric Repulsion

Origin of the Bürgi‐Dunitz Angle

S N 2 versus E2 Competition of Cyclic Ethers

Origin of the Bürgi‐Dunitz Angle

Probing Polar‐π Interactions Between Tetrazoles and Aromatic Rings **

Intermolecular Covalent Interactions: Nature and Directionality

The Search for Enhanced σ‐Donor Ligands to Stabilize Boron‐Boron Multiple Bonds

Palladium-catalyzed activation of H n A–AH n bonds (AH n = CH 3, NH 2, OH, F)

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn =N, P, As)

Insertion of CO2 and CS2 into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer

How Bases Catalyze Diels‐Alder Reactions

The abnormally long and weak methylidyne C–H bond

Methyl Substitution Destabilizes Alkyl Radicals

Methyl Substitution Destabilizes Alkyl Radicals

How Ionization Catalyzes Diels–Alder Reactions

How Ionization Catalyzes Diels–Alder Reactions

C−X Bond Activation by Palladium: Steric Shielding versus Steric Attraction

How Ionization Catalyzes Diels‐Alder Reactions

Corrigendum: Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions

C (sp n)−X (n=1–3) Bond Activation by Palladium

B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order

Probing the Lewis Acidity of Boronic Acids through Interactions with Arene Substituents

C (sp n)−X (n=1–3) Bond Activation by Iron

Palladium‐Catalyzed Activation of Carbon–Halogen Bonds: Electrostatics‐Controlled Reactivity

B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order

Front Cover: B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order (ChemistryOpen 2/2022)

The Chemical Bond: When Atom Size instead of Electronegativity Difference Determines Trend in Bond Strength

The Chemical Bond: When Atom Size Instead of Electronegativity Difference Determines Trend in Bond Strength

Radical Scavenging Potential of the Phenothiazine Scaffold: A Computational Analysis

Origin of the α‐Effect in S N 2 Reactions

Origin of the α‐Effect in S N 2 Reactions

Origin of the α‐Effect in S N 2 Reactions

Origin of the α‐Effect in S N 2 Reactions

Lewis Acid‐Catalyzed Diels‐Alder Reactions: Reactivity Trends across the Periodic Table

How Lewis Acids Catalyze Ene Reactions

On the Origin of Regioselectivity in Palladium‐Catalyzed Oxidation of Glucosides

Proton Transfer and S N 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx

Proton Transfer and S N 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx

The Gauche Effect in XCH 2 CH 2 X Revisited

A Quantitative Molecular Orbital Perspective of the Chalcogen Bond

Switch From Pauli‐Lowering to LUMO‐Lowering Catalysis in Brønsted Acid‐Catalyzed Aza‐Diels‐Alder Reactions

A Quantitative Molecular Orbital Perspective of the Chalcogen Bond

Front Cover: A Quantitative Molecular Orbital Perspective of the Chalcogen Bond (4/2021)

Nature of Alkali‐ and Coinage‐Metal Bonds versus Hydrogen Bonds

Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement

Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement

Do Sulfonamides Interact with Aromatic Rings?

How Oriented External Electric Fields Modulate Reactivity

How Oriented External Electric Fields Modulate Reactivity

Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length

Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length

Bismutamide als einfache Vermittler hochselektiver Pn−Pn‐Radikal‐Kupplungsreaktionen (Pn=N, P, As)

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As)

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As)