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Matthias Rudolph (1975-)

Chemiker

Name	Matthias Rudolph
Zeit	1975- (Lebensdaten)
Ort	Stuttgart (Geburtsort) Deutschland
Geschlecht	männlich
Akademischer Grad bzw. Titel	Dr. rer. nat.
Beruf	Chemiker (charakteristischer Beruf)
Variante	Matthias Christian Rudolph Matthias C. Rudolph
Beziehung	Organisch-Chemisches Institut (Heidelberg)
Datensatztyp	Person
GND-Nummer	136790380
Datensatz-ID	136790380
Beteiligt an alle anzeigen Dynamic Coordination Behavior of a Structurally Constrained, Nucleophilic Sn (II) Towards Gold (I) Cyclopentannulated Dihydrotetraazapentacenes A Radical Chain: Mononuclear “Gold Only” Photocatalysis Access to Unsymmetrically Substituted Diaryl Gold N‐Acyclic Carbene (NAC) and N‐Heterocyclic Carbene (NHC) Complexes via the Isonitrile Route Water Can Accelerate Homogeneous Gold Catalysis Environmentally Friendly, Photochemical Access to [ N ∧ C ∧ N ]Au III Pincer Complexes By Oxidative Addition Mechanochemical Gold(III)‐Carbon Bond Formation Expanded Ring NHC Silver Carboxylate Complexes as Efficient and Reusable Catalysts for the Carboxylative Cyclization of Unsubstituted Propargylic Derivatives A Metal‐Free Direct Arene C−H Amination Gold Catalysis Meets Materials Science – A New Approach to π‐Extended Indolocarbazoles A Gold‐Catalyzed Acid‐Assisted Regioselective Cyclization for the Synthesis of Polysubstituted Oxazoles Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium‐Catalysed C−H Amidation Synthesis of Fulvene Vinyl Ethers by Gold Catalysis Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives Gold (I) Complexes with Eight‐Membered NHC Ligands: Synthesis, Structures and Catalytic Activity Gold‐Catalyzed Intermolecular Oxidative Diyne Cyclizations via 1,6‐Carbene Transfer Gold‐Catalyzed Regiospecific Annulation of Unsymmetrically Substituted 1,5‐Diynes for the Precise Synthesis of Bispentalenes Gold‐Catalyzed C (sp 2)−C (sp) Coupling by Alkynylation through Oxidative Addition of Bromoalkynes Gold‐Catalyzed Cyclisation by 1,4‐Dioxidation AuBr 3 ‐Catalyzed Chemoselective Annulation of Isocyanates with 2 H ‐Azirine Dual Gold/Silver Catalysis Involving Alkynylgold (III) Intermediates Formed by Oxidative Addition and Silver‐Catalyzed C−H Activation for the Direct Alkynylation of Cyclopropenes Sulfilimines as Versatile Nitrene Transfer Reagents: Facile Access to Diverse Aza‐Heterocycles A Silver‐Catalyzed Modular Intermolecular Access to 6,6‐Spiroketals Gold‐Catalyzed Stereoselective Domino Cyclization/Alkynylation of N ‐Propargylcarboxamides with Benziodoxole Reagents for the Synthesis of Alkynyloxazolines Gold‐Catalyzed Synthesis of 2,5‐Disubstituted Oxazoles from Carboxamides and Propynals Strategic Approach on N ‐Oxides in Gold Catalysis – A Case Study Gold‐Catalyzed Hydrofunctionalizations and Spiroketalizations of Alkynes as Key Steps in Total Synthesis Different Selectivities in the Insertions into C (sp 2)−H Bonds: Benzofulvenes by Dual Gold Catalysis Competition Experiments The Gold (I)‐Mediated Domino Reaction to Fused Diphenyl Phosphoniumfluorenes: Mechanistic Consequences for Gold‐Catalyzed Hydroarylations and Application in Solar Cells The Gold (I)‐Mediated Domino Reaction to Fused Diphenyl Phosphoniumfluorenes: Mechanistic Consequences for Gold‐Catalyzed Hydroarylations and Application in Solar Cells A Golden Access to Acenopentalenes Direkter Zugang zu Azulenen über eine Gold‐katalysierte Dimerisierung von Diarylalkinen An Industrial Perspective on Counter Anions in Gold Catalysis: On Alternative Counter Anions An Industrial Perspective on Counter Anions in Gold Catalysis: Underestimated with Respect to “Ligand Effects” A Structure‐Based Activity Study of Highly Active Unsymmetrically Substituted NHC Gold (I) Catalysts Gold-based frustrated Lewis acid/base pairs (FLPs) Gold‐Catalyzed Formal Cyclisation/Dimerization of Thiophene‐Tethered Diynes Intramolecular anti ‐Phosphinoauration of Alkynes: An FLP‐Motivated Approach to Stable Aurated Phosphindolium Complexes Dual Gold (I)‐catalyzed Cyclization of Dialkynyl Pyridinium Salts On the Gold‐Catalyzed Generation of Vinyl Cations from 1,5‐Diynes On the Gold‐Catalyzed Generation of Phenyl Cations from 1,5‐Diynes Total Synthesis of (±)‐Dihydroisosubamol Dual Gold Catalysis: Synthesis of Fluorene Derivatives from Diynes Facile Synthesis of Functionalized Carbene Metal Complexes from Coordinated Isonitriles New Pathways for the Dual Gold‐Catalyzed Cyclization of Diynes Intermolecular Photocatalyzed Heck‐like Coupling of Unactivated Alkyl Bromides by a Dinuclear Gold Complex Gold‐katalysierte Synthese von Chinolinen aus Propargylsilylethern und Anthranilen über die Umpolung eines Goldcarben‐Kohlenstoffatoms Monofluoralkenylierung von Dimethylaminoverbindungen durch Radikal‐Radikal‐Kreuzkupplung Gold‐katalysierte 1,2‐Difunktionalisierung von Alkinen mit sichtbarem Licht ohne zusätzlichen Photosensibilisator Gold‐Catalyzed Synthesis of Quinolines from Propargyl Silyl Ethers and Anthranils through the Umpolung of a Gold Carbene Carbon Monofluoroalkenylation of Dimethylamino Compounds through Radical–Radical Cross‐Coupling Gold‐Catalyzed Highly Selective Photoredox C (sp 2)−H Difluoroalkylation and Perfluoroalkylation of Hydrazones Synthesis and Properties of Hydrazino Amino Acyclic Carbenes of Gold (I), Platinum (II), Palladium (II) and Rhodium (III) Conjugated Vinylgold (I)‐Vinylideneruthenium (II) Complexes and Related Organoruthenium Compounds: Stable Analogues of Intermediates Proposed in Dual Gold Catalysis A Gold‐Catalyzed A3 Coupling/Cyclization/Elimination Sequence as Versatile Tool for the Synthesis of Furfuryl Alcohol Derivatives from Glyceraldehyde and Alkynes A Highly Efficient Gold‐Catalyzed Photoredox α‐C (sp 3) H Alkynylation of Tertiary Aliphatic Amines with Sunlight CO Extrusion in Homogeneous Gold Catalysis: Reactivity of Gold Acyl Species Generated through Water Addition to Gold Vinylidenes † From Isonitriles to Unsaturated NHC Complexes of Gold, Palladium and Platinum Scope and Limitations of the Intermolecular Furan‐Yne Cyclization

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Katalog der Deutschen Nationalbibliothek

Matthias Rudolph (1975-)

Dynamic Coordination Behavior of a Structurally Constrained, Nucleophilic Sn (II) Towards Gold (I)

Cyclopentannulated Dihydrotetraazapentacenes

A Radical Chain: Mononuclear “Gold Only” Photocatalysis

Access to Unsymmetrically Substituted Diaryl Gold N‐Acyclic Carbene (NAC) and N‐Heterocyclic Carbene (NHC) Complexes via the Isonitrile Route

Water Can Accelerate Homogeneous Gold Catalysis

Environmentally Friendly, Photochemical Access to [ N ∧ C ∧ N ]Au III Pincer Complexes By Oxidative Addition

Mechanochemical Gold(III)‐Carbon Bond Formation

Expanded Ring NHC Silver Carboxylate Complexes as Efficient and Reusable Catalysts for the Carboxylative Cyclization of Unsubstituted Propargylic Derivatives

A Metal‐Free Direct Arene C−H Amination

Gold Catalysis Meets Materials Science – A New Approach to π‐Extended Indolocarbazoles

A Gold‐Catalyzed Acid‐Assisted Regioselective Cyclization for the Synthesis of Polysubstituted Oxazoles

Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium‐Catalysed C−H Amidation

Synthesis of Fulvene Vinyl Ethers by Gold Catalysis

Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives

Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives

Gold (I) Complexes with Eight‐Membered NHC Ligands: Synthesis, Structures and Catalytic Activity

Gold‐Catalyzed Intermolecular Oxidative Diyne Cyclizations via 1,6‐Carbene Transfer

Gold‐Catalyzed Regiospecific Annulation of Unsymmetrically Substituted 1,5‐Diynes for the Precise Synthesis of Bispentalenes

Gold‐Catalyzed C (sp 2)−C (sp) Coupling by Alkynylation through Oxidative Addition of Bromoalkynes

Gold‐Catalyzed Cyclisation by 1,4‐Dioxidation

AuBr 3 ‐Catalyzed Chemoselective Annulation of Isocyanates with 2 H ‐Azirine

Dual Gold/Silver Catalysis Involving Alkynylgold (III) Intermediates Formed by Oxidative Addition and Silver‐Catalyzed C−H Activation for the Direct Alkynylation of Cyclopropenes

Sulfilimines as Versatile Nitrene Transfer Reagents: Facile Access to Diverse Aza‐Heterocycles

A Silver‐Catalyzed Modular Intermolecular Access to 6,6‐Spiroketals

Gold‐Catalyzed Stereoselective Domino Cyclization/Alkynylation of N ‐Propargylcarboxamides with Benziodoxole Reagents for the Synthesis of Alkynyloxazolines

Gold‐Catalyzed Synthesis of 2,5‐Disubstituted Oxazoles from Carboxamides and Propynals

Strategic Approach on N ‐Oxides in Gold Catalysis – A Case Study

Gold‐Catalyzed Hydrofunctionalizations and Spiroketalizations of Alkynes as Key Steps in Total Synthesis

Different Selectivities in the Insertions into C (sp 2)−H Bonds: Benzofulvenes by Dual Gold Catalysis Competition Experiments

The Gold (I)‐Mediated Domino Reaction to Fused Diphenyl Phosphoniumfluorenes: Mechanistic Consequences for Gold‐Catalyzed Hydroarylations and Application in Solar Cells

The Gold (I)‐Mediated Domino Reaction to Fused Diphenyl Phosphoniumfluorenes: Mechanistic Consequences for Gold‐Catalyzed Hydroarylations and Application in Solar Cells

A Golden Access to Acenopentalenes

Direkter Zugang zu Azulenen über eine Gold‐katalysierte Dimerisierung von Diarylalkinen

An Industrial Perspective on Counter Anions in Gold Catalysis: On Alternative Counter Anions

An Industrial Perspective on Counter Anions in Gold Catalysis: Underestimated with Respect to “Ligand Effects”

A Structure‐Based Activity Study of Highly Active Unsymmetrically Substituted NHC Gold (I) Catalysts

Gold-based frustrated Lewis acid/base pairs (FLPs)

Gold‐Catalyzed Formal Cyclisation/Dimerization of Thiophene‐Tethered Diynes

Intramolecular anti ‐Phosphinoauration of Alkynes: An FLP‐Motivated Approach to Stable Aurated Phosphindolium Complexes

Dual Gold (I)‐catalyzed Cyclization of Dialkynyl Pyridinium Salts

On the Gold‐Catalyzed Generation of Vinyl Cations from 1,5‐Diynes

On the Gold‐Catalyzed Generation of Phenyl Cations from 1,5‐Diynes

Total Synthesis of (±)‐Dihydroisosubamol

Dual Gold Catalysis: Synthesis of Fluorene Derivatives from Diynes

Facile Synthesis of Functionalized Carbene Metal Complexes from Coordinated Isonitriles

New Pathways for the Dual Gold‐Catalyzed Cyclization of Diynes

Intermolecular Photocatalyzed Heck‐like Coupling of Unactivated Alkyl Bromides by a Dinuclear Gold Complex

Gold‐katalysierte Synthese von Chinolinen aus Propargylsilylethern und Anthranilen über die Umpolung eines Goldcarben‐Kohlenstoffatoms

Monofluoralkenylierung von Dimethylaminoverbindungen durch Radikal‐Radikal‐Kreuzkupplung

Gold‐katalysierte 1,2‐Difunktionalisierung von Alkinen mit sichtbarem Licht ohne zusätzlichen Photosensibilisator

Gold‐Catalyzed Synthesis of Quinolines from Propargyl Silyl Ethers and Anthranils through the Umpolung of a Gold Carbene Carbon

Monofluoroalkenylation of Dimethylamino Compounds through Radical–Radical Cross‐Coupling

Gold‐Catalyzed Highly Selective Photoredox C (sp 2)−H Difluoroalkylation and Perfluoroalkylation of Hydrazones

Synthesis and Properties of Hydrazino Amino Acyclic Carbenes of Gold (I), Platinum (II), Palladium (II) and Rhodium (III)

Conjugated Vinylgold (I)‐Vinylideneruthenium (II) Complexes and Related Organoruthenium Compounds: Stable Analogues of Intermediates Proposed in Dual Gold Catalysis

A Gold‐Catalyzed A3 Coupling/Cyclization/Elimination Sequence as Versatile Tool for the Synthesis of Furfuryl Alcohol Derivatives from Glyceraldehyde and Alkynes

A Highly Efficient Gold‐Catalyzed Photoredox α‐C (sp 3) H Alkynylation of Tertiary Aliphatic Amines with Sunlight

CO Extrusion in Homogeneous Gold Catalysis: Reactivity of Gold Acyl Species Generated through Water Addition to Gold Vinylidenes †

From Isonitriles to Unsaturated NHC Complexes of Gold, Palladium and Platinum

Scope and Limitations of the Intermolecular Furan‐Yne Cyclization