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Lutz Greb

Name	Lutz Greb
Place	Traben-Trarbach Heidelberg (Wirkungsort) Deutschland
Academic degree	Dr. rer. nat. (an der Fakultät für Chemie und Biowissenschaften des Karlsruher Instituts für Technologie (KIT)) (2013)
Related	Anorganisch-Chemisches Institut (Heidelberg) (2016-) Chemie (Studienfach)
Record type	Person
GND-Identifier	1043619879
Record ID	1043619879
Involved in show all Critical Evaluation of Childs Method for the NMR Spectroscopic Scaling of Effective Lewis Acidity: Limitations and Resolution of Earlier Discrepancies A Benchmark Study of DFT‐Computed p ‐Block Element Lewis Pair Formation Enthalpies Against Experimental Calorimetric Data Dynamic Coordination Behavior of a Structurally Constrained, Nucleophilic Sn (II) Towards Gold (I) Structural Flexibility is a Decisive Factor in FLP Dihydrogen Cleavage with Tetrahedral Lewis Acids: A Silane Case Study Conformational and Substitution Effects on the Donor and Reducing Strength of Tin (II) Porphyrinogens Supramolecular trapping of a cationic all-metal σ-aromatic Bi4} ring How to Deal with Charge in the Ranking of Lewis Acidity: Critical Evaluation of an Extensive Set of Cationic Lewis Acids How to Deal with Charge in the Ranking of Lewis Acidity: Critical Evaluation of an Extensive Set of Cationic Lewis Acids Predicting Lewis Acidity: Machine Learning the Fluoride Ion Affinity of p ‐Block‐Atom‐Based Molecules Predicting Lewis Acidity: Machine Learning the Fluoride Ion Affinity of p ‐Block‐Atom‐Based Molecules Silicon‐Catalyzed Depolymerization of Polyethers: Pushing Scope, Practicability and Mechanistic Understanding Leveraging Structural Constraint for Lewis Superacidity and Element-Ligand-Cooperativity of p-Block Elements Structural Constraint and Flexibility in the Chemistry of Lewis-Acidic p-Block Atom-Based Molecules Neutral and Anionic Square Planar Palladium (0) Complexes Stabilized by a Silicon Z‐Type Ligand Neutral and Anionic Square Planar Palladium (0) Complexes Stabilized by a Silicon Z‐Type Ligand p-Block Element Catecholates: Lewis Superacidic, Constitutionally Dynamic and Redox-Active Catechol‐Mediated Redox‐Neutral One‐pot Transformation of SiO 2 into SiPh 4 Trialkoxysilane Exchange: Scope, Mechanism, Cryptates and pH‐Response Trialkoxysilane Exchange: Scope, Mechanism, Cryptates and pH‐Response Redox‐Active Lewis Pairs Yield Diradicaloids and Enable Modular Control of the Diradical Character Synthesis and Characterization of Silicon Polyoxolenes Bis (amidophenolato) phosphonium: Si−H Hydride Abstraction and Phosphorus‐Ligand Cooperative Activation of C−C Multiple Bonds Silicon Catalyzed C−O Bond Ring Closing Metathesis of Polyethers Silicon Catalyzed C−O Bond Ring Closing Metathesis of Polyethers Calix (4) pyrrolato Stibenium: Lewis Superacidity by Antimony (III)‐Antimony (V) Electromerism Calix (4) pyrrolato Stibenium: Lewis Superacidity by Antimony (III)‐Antimony (V) Electromerism Dihydrogen Activation with a Neutral, Intermolecular Silicon (IV)‐Amine Frustrated Lewis Pair Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis Calix (4) pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers Calix (4) pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers Calix (4) pyrrolatostannat (II): Ein Tetraamidozinn (II) dianion als starker, metallzentrierter σ‐Donor Calix (4) pyrrolato Stannate (II): A Tetraamido Tin (II) Dianion and Strong Metal‐Centered σ‐Donor Struktur und Reaktivität von Bis(catecholato)silanen Valence Tautomerism of p‐Block Element Compounds – An Eligible Phenomenon for Main Group Catalysis? What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann–Beckett Method What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann–Beckett Method Bis(perfluoropinacolato)silan: Eine neutrale Lewis‐Supersäure aktiviert Si−F‐Bindungen Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si−F Bonds Disauerstoffaktivierung und Pyrrol‐α‐Spaltung mit Calix[4]pyrrolatoaluminaten: Enzymmodell durch strukturellen Zwang Dioxygen Activation and Pyrrole α‐Cleavage with Calix[4]pyrrolato Aluminates: Enzyme Model by Structural Constraint Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon Multidimensional Lewis Acidity: A Consistent Data Set of Chloride, Hydride, Methide, Water and Ammonia Affinities for 183 p‐Block Element Lewis Acids Calix[4]pyrrolato Aluminates: The Effect of Ligand Modification on the Reactivity of Square‐Planar Aluminum Anions Planare Silizium(IV)-Verbindungen (ptSi) und planare Aluminate (ptAl-). Von strukturellen Kuriositäten hin zu anwendbaren Reaktivitäten Element‐Ligand Cooperativity with p‐Block Elements An Extensive Set of Accurate Fluoride Ion Affinities for p ‐Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst An Air‐Stable, Neutral Phenothiazinyl Radical with Substantial Radical Stabilization Energy (Si (O 2 C 6 F 4) 2) 14: Selbstassemblierung eines perfluorierten makrocyclischen Wirts durch Si‐O‐Bindungsmetathese mit niedriger Barriere Metal–Ligand Cooperativity of the Calix (4) pyrrolato Aluminate: Triggerable C−C Bond Formation and Rate Control in Catalysis Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile (Si (O 2 C 6 F 4) 2) 14: Self‐Assembly of a Giant Perfluorinated Macrocyclic Host by Low‐Barrier Si−O Bond Metathesis Bis (perchlorocatecholato) germane: Hard and Soft Lewis Superacid with Unlimited Water Stability Metal–Ligand Cooperativity of the Calix (4) pyrrolato Aluminate: Triggerable C−C Bond Formation and Rate Control in Catalysis Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile Substituentenvermittelte Reaktivitätsmodulation von aminosubstituierten Silizium(IV)-Verbindungen On the Metal Cooperativity in a Dinuclear Copper–Guanidine Complex for Aliphatic C−H Bond Cleavage by Dioxygen Siliziumtris (perchloro) dioxolen: ein neutrales Triplett‐Diradikal Silicon Tris (perchloro) dioxolene: A Neutral Triplet Diradical

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Lutz Greb

Critical Evaluation of Childs Method for the NMR Spectroscopic Scaling of Effective Lewis Acidity: Limitations and Resolution of Earlier Discrepancies

A Benchmark Study of DFT‐Computed p ‐Block Element Lewis Pair Formation Enthalpies Against Experimental Calorimetric Data

Dynamic Coordination Behavior of a Structurally Constrained, Nucleophilic Sn (II) Towards Gold (I)

Structural Flexibility is a Decisive Factor in FLP Dihydrogen Cleavage with Tetrahedral Lewis Acids: A Silane Case Study

Conformational and Substitution Effects on the Donor and Reducing Strength of Tin (II) Porphyrinogens

Supramolecular trapping of a cationic all-metal σ-aromatic Bi4} ring

How to Deal with Charge in the Ranking of Lewis Acidity: Critical Evaluation of an Extensive Set of Cationic Lewis Acids

How to Deal with Charge in the Ranking of Lewis Acidity: Critical Evaluation of an Extensive Set of Cationic Lewis Acids

Predicting Lewis Acidity: Machine Learning the Fluoride Ion Affinity of p ‐Block‐Atom‐Based Molecules

Predicting Lewis Acidity: Machine Learning the Fluoride Ion Affinity of p ‐Block‐Atom‐Based Molecules

Silicon‐Catalyzed Depolymerization of Polyethers: Pushing Scope, Practicability and Mechanistic Understanding

Leveraging Structural Constraint for Lewis Superacidity and Element-Ligand-Cooperativity of p-Block Elements

Structural Constraint and Flexibility in the Chemistry of Lewis-Acidic p-Block Atom-Based Molecules

Neutral and Anionic Square Planar Palladium (0) Complexes Stabilized by a Silicon Z‐Type Ligand

Neutral and Anionic Square Planar Palladium (0) Complexes Stabilized by a Silicon Z‐Type Ligand

p-Block Element Catecholates: Lewis Superacidic, Constitutionally Dynamic and Redox-Active

Catechol‐Mediated Redox‐Neutral One‐pot Transformation of SiO 2 into SiPh 4

Trialkoxysilane Exchange: Scope, Mechanism, Cryptates and pH‐Response

Trialkoxysilane Exchange: Scope, Mechanism, Cryptates and pH‐Response

Redox‐Active Lewis Pairs Yield Diradicaloids and Enable Modular Control of the Diradical Character

Synthesis and Characterization of Silicon Polyoxolenes

Bis (amidophenolato) phosphonium: Si−H Hydride Abstraction and Phosphorus‐Ligand Cooperative Activation of C−C Multiple Bonds

Silicon Catalyzed C−O Bond Ring Closing Metathesis of Polyethers

Silicon Catalyzed C−O Bond Ring Closing Metathesis of Polyethers

Calix (4) pyrrolato Stibenium: Lewis Superacidity by Antimony (III)‐Antimony (V) Electromerism

Calix (4) pyrrolato Stibenium: Lewis Superacidity by Antimony (III)‐Antimony (V) Electromerism

Dihydrogen Activation with a Neutral, Intermolecular Silicon (IV)‐Amine Frustrated Lewis Pair

Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis

Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis

Calix (4) pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers

Calix (4) pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers

Calix (4) pyrrolatostannat (II): Ein Tetraamidozinn (II) dianion als starker, metallzentrierter σ‐Donor

Calix (4) pyrrolato Stannate (II): A Tetraamido Tin (II) Dianion and Strong Metal‐Centered σ‐Donor

Struktur und Reaktivität von Bis(catecholato)silanen

Valence Tautomerism of p‐Block Element Compounds – An Eligible Phenomenon for Main Group Catalysis?

What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann–Beckett Method

What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann–Beckett Method

Bis(perfluoropinacolato)silan: Eine neutrale Lewis‐Supersäure aktiviert Si−F‐Bindungen

Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si−F Bonds

Disauerstoffaktivierung und Pyrrol‐α‐Spaltung mit Calix[4]pyrrolatoaluminaten: Enzymmodell durch strukturellen Zwang

Dioxygen Activation and Pyrrole α‐Cleavage with Calix[4]pyrrolato Aluminates: Enzyme Model by Structural Constraint

Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon

Multidimensional Lewis Acidity: A Consistent Data Set of Chloride, Hydride, Methide, Water and Ammonia Affinities for 183 p‐Block Element Lewis Acids

Calix[4]pyrrolato Aluminates: The Effect of Ligand Modification on the Reactivity of Square‐Planar Aluminum Anions

Planare Silizium(IV)-Verbindungen (ptSi) und planare Aluminate (ptAl-). Von strukturellen Kuriositäten hin zu anwendbaren Reaktivitäten

Element‐Ligand Cooperativity with p‐Block Elements

An Extensive Set of Accurate Fluoride Ion Affinities for p ‐Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors

Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst

An Air‐Stable, Neutral Phenothiazinyl Radical with Substantial Radical Stabilization Energy

(Si (O 2 C 6 F 4) 2) 14: Selbstassemblierung eines perfluorierten makrocyclischen Wirts durch Si‐O‐Bindungsmetathese mit niedriger Barriere

Metal–Ligand Cooperativity of the Calix (4) pyrrolato Aluminate: Triggerable C−C Bond Formation and Rate Control in Catalysis

Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile

(Si (O 2 C 6 F 4) 2) 14: Self‐Assembly of a Giant Perfluorinated Macrocyclic Host by Low‐Barrier Si−O Bond Metathesis

Bis (perchlorocatecholato) germane: Hard and Soft Lewis Superacid with Unlimited Water Stability

Metal–Ligand Cooperativity of the Calix (4) pyrrolato Aluminate: Triggerable C−C Bond Formation and Rate Control in Catalysis

Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile

Substituentenvermittelte Reaktivitätsmodulation von aminosubstituierten Silizium(IV)-Verbindungen

On the Metal Cooperativity in a Dinuclear Copper–Guanidine Complex for Aliphatic C−H Bond Cleavage by Dioxygen

Siliziumtris (perchloro) dioxolen: ein neutrales Triplett‐Diradikal

Silicon Tris (perchloro) dioxolene: A Neutral Triplet Diradical