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Stefano Zacchini

Chemiker

Name	Stefano Zacchini
Time	1998- (Wirkungsdaten)
Place	Italien
Gender	männlich
Academic degree	Prof. Dr.
Profession	Chemiker (characteristic profession) Hochschullehrer
Related	Università di Bologna
Source	https://www.unibo.it/sitoweb/stefano.zacchini (Stand: 11.01.2024)
Record type	Person
GND-Identifier	1276028849
Record ID	1276028849
Involved in show all Atomically Precise Rhodium‐Gold Carbonyl Nanoclusters: In‐Depth Synthesis and Multivalence Investigation of (Rh 16 Au 6 (CO) 36) 6−, and its Correlation with (Rh 10 Au (CO) 26) 3− Multisite Amino‐Allylidene Ligands from Thermal CO Elimination in Diiron Complexes and Catalytic Activity in Hydroboration Reactions Role of Alkylated 2,6‐bis (tetrazol‐5‐yl) pyridyl Ligands and Iron (II) Salts in Selecting Spin Crossover Complexes Designing Ionic Ir (III) Cyclometalated Complexes as Photocatalysts for Light Assisted ATRP of MMA. A Combined Experimental and Mechanistic Study Engineering ORR Electrocatalysts from Co 8 Pt 4 Carbonyl Clusters via ZIF‐8 Templating Cover Feature: Multisite Amino‐Allylidene Ligands from Thermal CO Elimination in Diiron Complexes and Catalytic Activity in Hydroboration Reactions (ChemCatChem 18/2024) Iminopyridine Copper Complex‐Based Catalysts for 1,3‐Dienes Stereospecific Polymerization Ruthenium (II) Tris‐Pyrazolylmethane Complexes in Transfer Hydrogenation Reactions Easily Available, Amphiphilic Diiron Cyclopentadienyl Complexes Exhibit in Vitro Anticancer Activity in 2D and 3D Human Cancer Cells through Redox Modulation Triggered by CO Release Bimetallic Fe–Ir and Trimetallic Fe–Ir–Au Carbonyl Clusters Containing Hydride and/or Phosphine Ligands: Syntheses, Structures and DFT Studies Construction of a Functionalized Selenophene‐Allylidene Ligand via Alkyne Double Action at a Diiron Complex A Comparative Experimental and Computational Study of Heterometallic Fe‐M (M = Cu, Ag, Au) Carbonyl Clusters Containing N‐Heterocyclic Carbene Ligands Imidazolium Salts of Ruthenium Anionic Cyclopentadienone Complexes: Ion Pair for Bifunctional Catalysis in Ionic Liquids Bypassing the Inertness of Aziridine/CO 2 Systems to Access 5‐Aryl‐2‐Oxazolidinones: Catalyst‐Free Synthesis Under Ambient Conditions Piano Stool Aminoalkylidene‐Ferracyclopentenone Complexes from Bimetallic Precursors: Synthesis and Cytotoxicity Data Bis‐conjugation of Bioactive Molecules to Cisplatin‐like Complexes through (2,2′‐Bipyridine)‐4,4′‐Dicarboxylic Acid with Optimal Cytotoxicity Profile Provided by the Combination Ethacrynic Acid/Flurbiprofen Synthesis and Characterization of Heterobimetallic Carbonyl Clusters with Direct Au‐Fe and Au···Au Interactions Supported by N ‐Heterocyclic Carbene and Phosphine Ligands Anticancer Potential of Diiron Vinyliminium Complexes Anticancer Potential of Diiron Vinyliminium Complexes Front Cover: Anticancer Potential of Diiron Vinyliminium Complexes (Chem. Eur. J. 65/2019) Functionalization, Modification, and Transformation of Platinum Chini Clusters Ruthenium Arene Complexes with α‐Aminoacidato Ligands: New Insights into Transfer Hydrogenation Reactions and Cytotoxic Behaviour Synthesis and Structural Characterization of Non‐Homoleptic Carbamato Complexes of V V and W VI and Their Facile Implantation onto Silica Surfaces Structural Characterization of a Fluorido‐Amide of Niobium, and Facile CO 2 Incorporation Affording a Fluorido‐Carbamate Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study Front Cover: Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study (Eur. J. Inorg. Chem. 8/2018) Cascade Reactions of α‐Phenylcinnamic Acid to Polycyclic Compounds Promoted by High Valent Transition Metal Halides Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium (II) Catalysts Front Cover Picture: Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium (II) Catalysts (Adv. Synth. Catal. 18/2018) Capping [H8−nNi42C8(CO)44]n− (n = 6, 7, 8) Octa-carbide Carbonyl Nanoclusters with [Ni(CO)] and [CuCl] Fragments Synthesis of the Highly Reduced (Fe 6 C (CO) 15) 4– Carbonyl Carbide Cluster and Its Reactions with H + and (Au (PPh 3)) + Front Cover: Synthesis of the Highly Reduced (Fe 6 C (CO) 15) 4– Carbonyl Carbide Cluster and Its Reactions with H + and (Au (PPh 3)) + (Eur. J. Inorg. Chem. 25/2017) Bimetallic Fe–Au Carbonyl Clusters Derived from Collman’s Reagent: Synthesis, Structure and DFT Analysis of Fe(CO)4(AuNHC)2 and [Au3Fe2(CO)8(NHC)2]− Growing the Molecular Architecture at Alkynyl (amino) carbene Ligands in Diiron µ‐Aminocarbyne Complexes Syntheses of (Pt 6 (CO) 8 (SnCl 2)(SnCl 3) 4) 4– and (Pt 6 (CO) 8 (SnCl 2)(SnCl 3) 2 (PPh 3) 2) 2– Platinum–Carbonyl Clusters Decorated by Sn II Fragments One‐Pot Intermolecular C–S Self‐Coupling of Dimethyl Sulfoxide Promoted by Molybdenum Pentachloride Reactivity of (WCl6) with Ethers: A Joint Computational, Spectroscopic and Crystallographic Study Bimetallic Fe–Cu Carbido Carbonyl Clusters Obtained from the Reactions of [Fe4C(CO)12Cu(MeCN)}2] with N-Donor Ligands The Chemistry of Ni–Sb Carbonyl Clusters – Synthesis and Characterization of the (Ni 19 Sb 4 (CO) 26) 4– Tetraanion and the Viologen Salts of (Ni 13 Sb 2 (CO) 24) n– Carbonyl Clusters ChemInform Abstract: Platinum Carbonyl Clusters Chemistry: Four Decades of Challenging Nanoscience Hydride Migration from a Triangular Face to a Tetrahedral Cavity in Tetranuclear Iron Carbonyl Clusters upon Coordination of (AuPPh 3) + Fragments † Hydride Migration from a Triangular Face to a Tetrahedral Cavity in Tetranuclear Iron Carbonyl Clusters upon Coordination of (AuPPh 3) + Fragments † Stable (M 2 F 11) – (M = Nb, Ta) Salts of Protonated 1,3‐Dimethoxybenzene C–S and C–Se Bond Formation at Bridging Vinyliminium Ligands in Diiron Complexes Iron‐Catalyzed Ferrocenylmethanol OH Substitution by S, N, P, and C Nucleophiles Oxido‐ and Sulfidoniobium (V) N, N ‐Diethylcarbamates: Synthesis, Characterization and DFT Study The Reactivity of Molybdenum Pentachloride with Ester Molecules: Ester Activation, Metal Reduction, and Synthesis of 1D Coordination Polymers Metal Segregation in Bimetallic Co Pd Carbide Carbonyl Clusters: Synthesis, Structure, Reactivity and Electrochemistry of (H 6− n Co 20 Pd 16 C 4 (CO) 48) n − (n =3–6) Unprecedented Transformation of Diiron Bridging Vinyliminium Ligands into Carboxyamido‐ and Alkylphosphonate‐Vinylalkylidenes Cage Rearrangements in Dodecanuclear Co–Pt Dicarbido Clusters Promoted by Redox Reactions ChemInform Abstract: Iron (II) Catalyzed Dehydrative Etherification of Alcohols: A Convenient Route to Ferrocenylmethanol‐Ethers. Using Metal Carbonyl Clusters To Develop a Molecular Approach towards Metal Nanoparticles C–H Activation in Diiron Bridging Vinyliminium Ligands: Reaction with CS 2 to Form New Zwitterionic Complexes Acting as Organometallic Ligands ChemInform Abstract: Using Metal Carbonyl Clusters to Develop a Molecular Approach Towards Metal Nanoparticles Synthesis, Structures and Electrochemistry of New Carbonylnickel Octacarbide Clusters: The Distorting Action of Carbide Atoms in the Growth of Ni Cages and the First Example of the Inclusion of a Carbon Atom within a (Distorted) Ni Octahedral Cage 5‐(2‐Thienyl) tetrazolates as Ligands for Ru II –Polypyridyl Complexes: Synthesis, Electrochemistry and Photophysical Properties γ‐Deprotonation of Bridging Vinyliminium Ligands: New Route to Aminobutadienylidene Diiron and Diruthenium Complexes Icosahedral Ga‐Centred Nickel Carbonyl Clusters: Synthesis and Characterization of (H 3– n Ni 12 (μ 12 ‐Ga)(CO) 22) n– (n = 2, 3) and (Ni 14.3 (μ 12 ‐Ga)(CO) 24.3) 3– Anions Preparation and Reactivity of Mono‐ and Dinuclear Derivatives of Niobium and Tantalum Pentahalides with Alkyl Aryl Ethers

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Katalog der Deutschen Nationalbibliothek

Stefano Zacchini

Atomically Precise Rhodium‐Gold Carbonyl Nanoclusters: In‐Depth Synthesis and Multivalence Investigation of (Rh 16 Au 6 (CO) 36) 6−, and its Correlation with (Rh 10 Au (CO) 26) 3−

Multisite Amino‐Allylidene Ligands from Thermal CO Elimination in Diiron Complexes and Catalytic Activity in Hydroboration Reactions

Role of Alkylated 2,6‐bis (tetrazol‐5‐yl) pyridyl Ligands and Iron (II) Salts in Selecting Spin Crossover Complexes

Designing Ionic Ir (III) Cyclometalated Complexes as Photocatalysts for Light Assisted ATRP of MMA. A Combined Experimental and Mechanistic Study

Engineering ORR Electrocatalysts from Co 8 Pt 4 Carbonyl Clusters via ZIF‐8 Templating

Cover Feature: Multisite Amino‐Allylidene Ligands from Thermal CO Elimination in Diiron Complexes and Catalytic Activity in Hydroboration Reactions (ChemCatChem 18/2024)

Iminopyridine Copper Complex‐Based Catalysts for 1,3‐Dienes Stereospecific Polymerization

Ruthenium (II) Tris‐Pyrazolylmethane Complexes in Transfer Hydrogenation Reactions

Easily Available, Amphiphilic Diiron Cyclopentadienyl Complexes Exhibit in Vitro Anticancer Activity in 2D and 3D Human Cancer Cells through Redox Modulation Triggered by CO Release

Bimetallic Fe–Ir and Trimetallic Fe–Ir–Au Carbonyl Clusters Containing Hydride and/or Phosphine Ligands: Syntheses, Structures and DFT Studies

Construction of a Functionalized Selenophene‐Allylidene Ligand via Alkyne Double Action at a Diiron Complex

A Comparative Experimental and Computational Study of Heterometallic Fe‐M (M = Cu, Ag, Au) Carbonyl Clusters Containing N‐Heterocyclic Carbene Ligands

Imidazolium Salts of Ruthenium Anionic Cyclopentadienone Complexes: Ion Pair for Bifunctional Catalysis in Ionic Liquids

Bypassing the Inertness of Aziridine/CO 2 Systems to Access 5‐Aryl‐2‐Oxazolidinones: Catalyst‐Free Synthesis Under Ambient Conditions

Piano Stool Aminoalkylidene‐Ferracyclopentenone Complexes from Bimetallic Precursors: Synthesis and Cytotoxicity Data

Bis‐conjugation of Bioactive Molecules to Cisplatin‐like Complexes through (2,2′‐Bipyridine)‐4,4′‐Dicarboxylic Acid with Optimal Cytotoxicity Profile Provided by the Combination Ethacrynic Acid/Flurbiprofen

Synthesis and Characterization of Heterobimetallic Carbonyl Clusters with Direct Au‐Fe and Au···Au Interactions Supported by N ‐Heterocyclic Carbene and Phosphine Ligands

Anticancer Potential of Diiron Vinyliminium Complexes

Anticancer Potential of Diiron Vinyliminium Complexes

Front Cover: Anticancer Potential of Diiron Vinyliminium Complexes (Chem. Eur. J. 65/2019)

Functionalization, Modification, and Transformation of Platinum Chini Clusters

Ruthenium Arene Complexes with α‐Aminoacidato Ligands: New Insights into Transfer Hydrogenation Reactions and Cytotoxic Behaviour

Synthesis and Structural Characterization of Non‐Homoleptic Carbamato Complexes of V V and W VI and Their Facile Implantation onto Silica Surfaces

Structural Characterization of a Fluorido‐Amide of Niobium, and Facile CO 2 Incorporation Affording a Fluorido‐Carbamate

Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study

Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study

Front Cover: Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study (Eur. J. Inorg. Chem. 8/2018)

Cascade Reactions of α‐Phenylcinnamic Acid to Polycyclic Compounds Promoted by High Valent Transition Metal Halides

Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium (II) Catalysts

Front Cover Picture: Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium (II) Catalysts (Adv. Synth. Catal. 18/2018)

Capping [H8−nNi42C8(CO)44]n− (n = 6, 7, 8) Octa-carbide Carbonyl Nanoclusters with [Ni(CO)] and [CuCl] Fragments

Synthesis of the Highly Reduced (Fe 6 C (CO) 15) 4– Carbonyl Carbide Cluster and Its Reactions with H + and (Au (PPh 3)) +

Front Cover: Synthesis of the Highly Reduced (Fe 6 C (CO) 15) 4– Carbonyl Carbide Cluster and Its Reactions with H + and (Au (PPh 3)) + (Eur. J. Inorg. Chem. 25/2017)

Bimetallic Fe–Au Carbonyl Clusters Derived from Collman’s Reagent: Synthesis, Structure and DFT Analysis of Fe(CO)4(AuNHC)2 and [Au3Fe2(CO)8(NHC)2]−

Growing the Molecular Architecture at Alkynyl (amino) carbene Ligands in Diiron µ‐Aminocarbyne Complexes

Syntheses of (Pt 6 (CO) 8 (SnCl 2)(SnCl 3) 4) 4– and (Pt 6 (CO) 8 (SnCl 2)(SnCl 3) 2 (PPh 3) 2) 2– Platinum–Carbonyl Clusters Decorated by Sn II Fragments

One‐Pot Intermolecular C–S Self‐Coupling of Dimethyl Sulfoxide Promoted by Molybdenum Pentachloride

Reactivity of (WCl6) with Ethers: A Joint Computational, Spectroscopic and Crystallographic Study

Bimetallic Fe–Cu Carbido Carbonyl Clusters Obtained from the Reactions of [Fe4C(CO)12Cu(MeCN)}2] with N-Donor Ligands

The Chemistry of Ni–Sb Carbonyl Clusters – Synthesis and Characterization of the (Ni 19 Sb 4 (CO) 26) 4– Tetraanion and the Viologen Salts of (Ni 13 Sb 2 (CO) 24) n– Carbonyl Clusters

ChemInform Abstract: Platinum Carbonyl Clusters Chemistry: Four Decades of Challenging Nanoscience

Hydride Migration from a Triangular Face to a Tetrahedral Cavity in Tetranuclear Iron Carbonyl Clusters upon Coordination of (AuPPh 3) + Fragments †

Hydride Migration from a Triangular Face to a Tetrahedral Cavity in Tetranuclear Iron Carbonyl Clusters upon Coordination of (AuPPh 3) + Fragments †

Stable (M 2 F 11) – (M = Nb, Ta) Salts of Protonated 1,3‐Dimethoxybenzene

C–S and C–Se Bond Formation at Bridging Vinyliminium Ligands in Diiron Complexes

Iron‐Catalyzed Ferrocenylmethanol OH Substitution by S, N, P, and C Nucleophiles

Oxido‐ and Sulfidoniobium (V) N, N ‐Diethylcarbamates: Synthesis, Characterization and DFT Study

The Reactivity of Molybdenum Pentachloride with Ester Molecules: Ester Activation, Metal Reduction, and Synthesis of 1D Coordination Polymers

Metal Segregation in Bimetallic Co Pd Carbide Carbonyl Clusters: Synthesis, Structure, Reactivity and Electrochemistry of (H 6− n Co 20 Pd 16 C 4 (CO) 48) n − (n =3–6)

Unprecedented Transformation of Diiron Bridging Vinyliminium Ligands into Carboxyamido‐ and Alkylphosphonate‐Vinylalkylidenes

Cage Rearrangements in Dodecanuclear Co–Pt Dicarbido Clusters Promoted by Redox Reactions

ChemInform Abstract: Iron (II) Catalyzed Dehydrative Etherification of Alcohols: A Convenient Route to Ferrocenylmethanol‐Ethers.

Using Metal Carbonyl Clusters To Develop a Molecular Approach towards Metal Nanoparticles

C–H Activation in Diiron Bridging Vinyliminium Ligands: Reaction with CS 2 to Form New Zwitterionic Complexes Acting as Organometallic Ligands

ChemInform Abstract: Using Metal Carbonyl Clusters to Develop a Molecular Approach Towards Metal Nanoparticles

Synthesis, Structures and Electrochemistry of New Carbonylnickel Octacarbide Clusters: The Distorting Action of Carbide Atoms in the Growth of Ni Cages and the First Example of the Inclusion of a Carbon Atom within a (Distorted) Ni Octahedral Cage

5‐(2‐Thienyl) tetrazolates as Ligands for Ru II –Polypyridyl Complexes: Synthesis, Electrochemistry and Photophysical Properties

γ‐Deprotonation of Bridging Vinyliminium Ligands: New Route to Aminobutadienylidene Diiron and Diruthenium Complexes

Icosahedral Ga‐Centred Nickel Carbonyl Clusters: Synthesis and Characterization of (H 3– n Ni 12 (μ 12 ‐Ga)(CO) 22) n– (n = 2, 3) and (Ni 14.3 (μ 12 ‐Ga)(CO) 24.3) 3– Anions

Preparation and Reactivity of Mono‐ and Dinuclear Derivatives of Niobium and Tantalum Pentahalides with Alkyl Aryl Ethers